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The original Knight of the White Orchid appeared in Shards of Alara, in 2008.
The original art was by Mark Zug.
Magic Origins
Midnight Hunt Commander
Commander 2020
Commander 2021
March of the Machine Commander
Duel Decks: Knights vs. Dragons
Crimson Vow Commander
Secret Lair Drop
Magic Origins Promos
Shards of Alara