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The original Knight of the White Orchid appeared in Shards of Alara, in 2008.
The original art was by Mark Zug.
Magic Origins
Midnight Hunt Commander
Commander 2020
Shards of Alara
Crimson Vow Commander
Commander 2021
March of the Machine Commander
Secret Lair Drop
Magic Origins Promos
Duel Decks: Knights vs. Dragons