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The original Knight of the White Orchid appeared in Shards of Alara, in 2008.
The original art was by Mark Zug.
Magic Origins
Crimson Vow Commander
Midnight Hunt Commander
Commander 2020
Shards of Alara
Commander 2021
Duel Decks: Knights vs. Dragons
March of the Machine Commander
Secret Lair Drop
Magic Origins Promos