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The original Knight of the White Orchid appeared in Shards of Alara, in 2008.
The original art was by Mark Zug.
Magic Origins
Crimson Vow Commander
March of the Machine Commander
Commander 2020
Commander 2021
Midnight Hunt Commander
Secret Lair Drop
Magic Origins Promos
Duel Decks: Knights vs. Dragons
Shards of Alara